Table 1 The five-level five-factor experimental design of 25 calibrations mixtures and the Latin Hypercube sampling design 13 validation set mixtures used in the chemometric methods
Mix no. | Calibration set (µg/mL) | |
|---|---|---|
LCZ | MLK | |
1 | 20 | 20 |
2 | 20 | 10 |
3 | 10 | 10 |
4 | 10 | 30 |
5 | 30 | 15 |
6 | 15 | 30 |
7 | 30 | 20 |
8 | 20 | 15 |
9 | 15 | 15 |
10 | 15 | 25 |
11 | 25 | 30 |
12 | 30 | 25 |
13 | 25 | 20 |
14 | 20 | 30 |
15 | 30 | 30 |
16 | 30 | 10 |
17 | 10 | 25 |
18 | 25 | 10 |
19 | 10 | 20 |
20 | 20 | 25 |
21 | 25 | 25 |
22 | 25 | 15 |
23 | 15 | 10 |
24 | 10 | 15 |
25 | 15 | 20 |
Mix no. | Validation set (µg/mL) | |
|---|---|---|
LCZ | MLK | |
1 | 19 | 16 |
2 | 22 | 27 |
3 | 13 | 12 |
4 | 22 | 13 |
5 | 18 | 26 |
6 | 11 | 22 |
7 | 16 | 29 |
8 | 17 | 21 |
9 | 27 | 11 |
10 | 27 | 24 |
11 | 13 | 27 |
12 | 29 | 19 |
13 | 23 | 21 |