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Table 1 Impact of high concentration and high current density attempt on the molar mass of synthesized polyvanillin and on key figures of merit for performance evaluation

From: Electroreduction of divanillin to polyvanillin in an electrochemical flow reactor

Current density (mA cm−2)

Divanillin concentration (mM)

γ

Mw

(g mol−1)

Mn

(g mol−1)

Mean cell voltage (V)

STY in kinetic zonea and (at X = 90%)

(kg l−1 h−1)

Es in kinetic zonea and (at X = 90%)

(kWh kg−1)

9

50

0.5

3588 ± 344

2207 ± 139

2.58 ± 0.02

0.072 ± 0.010

(0.052 ± 0.002)

0.938 ± 0.137 (1.277 ± 0.042)

54

300

0.5

3709

2094

3.63

0.471 (0.314)

1.191 (1.787)

  1. Parameters: 20 cm s−1, 8 F mol−1
  2. Error bars indicate standard deviations of at least 3 experiments
  3. aAfter conditioning phase of the electrode