Table 2 Selected bond lengths (Å) and bond angles (°) for complexes (1) and (2)
Selected bonds | Value (Å) | Selected angles | (°) | Selected bonds | Value (Å) | Selected angles | (°) |
|---|---|---|---|---|---|---|---|
Complex 1 | Complex 2 | ||||||
Pb1-O1 | 2.498(4) | O1 -Pb1-O2 | 47.27(15) | Pb1-O1 | 2.341(3) | O1-Pb1-O2 | 71.10(12) |
Pb1-O2 | 2.962(6) | O1 -Pb1-O3 | 71.84(15) | Pb1-O2 | 2.605(4) | O1-Pb1-O5 | 73.83(13) |
Pb1-O3 | 2.342(4) | O1 -Pb1-O4 | 73.97(14) | Pb1-O5 | 2.497(4) | O1-Pb1-O6 | 117.20(11) |
Pb1-O4 | 2.615(4) | O1 -Pb1-N1 | 76.85(17) | Pb1-O6 | 2.979(5) | O1-Pb1-N1 | 68.30(13) |
Pb1-N1 | 2.483(5) | O1 -Pb1-O3i | 140.79(14) | Pb1-N1 | 2.482(4) | O1-Pb1-O1i | 71.84(10) |
Pb1-O3i | 2.607(4) | O1 -Pb1-O6i | 141.42(15) | Pb1-O1i | 2.637(3) | O1-Pb1-O4i | 116.78(13) |
Pb1-O6_a | 2.812(5) | O2-Pb1-O3 | 115.33(15) | Pb1-O4i | 2.832(4) | O2-Pb1-O5 | 73.87(11) |
Pb2-O1 | 3.040(5) | O2-Pb1-O4 | 104.81(14) | Pb2-O1 | 2.848(3) | O2-Pb1-O6 | 103.69(12) |
Pb2-O3 | 2.857(4) | O2-Pb1-N1 | 77.78(16) | Pb2-O2 | 2.349(3) | O2-Pb1-N1 | 134.56(12) |
Pb2-O4 | 2.338(4) | O2-Pb1-O3i | 171.93(13) | Pb2-O3 | 2.687(5) | O1 i -Pb1-O2 | 81.26(10) |
Pb2-O5 | 2.770(6) | O2-Pb1-O6i | 102.58(15) | Pb2-O4 | 2.868(5) | O2-Pb1-O4i | 145.95(10) |
Pb2-O6 | 2.756(6) | O3-Pb1-O4 | 71.00(14) | Pb2-N2 | 2.448(4) | O5-Pb1-O6 | 46.74(13) |
Pb2-N2 | 2.447(5) | O3-Pb1-N1 | 68.09(15) | Pb2-N3 | 2.782(4) | O5-Pb1-N1 | 76.03(14) |
Pb2-N3 | 2.788(6) | O3-Pb1-O3i | 72.19(13) | Pb2-N4 | 2.720(5) | O1 i -Pb1-O5 | 142.56(12) |
Pb2-N4 | 2.747(6) | O3-Pb1-O6i | 116.12(16) | O4 i -Pb1-O5 | 139.70(12) | ||
O4-Pb1-N1 | 135.28(15) | O6-Pb1-N1 | 78.19(14) | ||||
O3 i -Pb1-O4 | 80.06(13) | O1 i -Pb1-O6 | 170.60(11) | ||||
O4-Pb1-O6i | 144.46(14) | O4 i -Pb1-O6 | 101.05(12) | ||||
O3 i -Pb1-N1 | 103.45(14) | O1 i -Pb1-N1 | 104.19(13) | ||||
O6 i -Pb1-N1 | 72.67(16) | O4 i-Pb1-N1 | 73.38(13) | ||||
O3 i -Pb1-O6i | 70.52(14) | O1 i -Pb1-O4i | 71.37(11) | ||||
O1-Pb2-O3 | 57.53(11) | O1-Pb2-O2 | 66.61(11) | ||||
O1-Pb2-O4 | 68.38(12) | O1-Pb2-O3 | 105.13(12) | ||||
O1-Pb2-O5 | 151.53(15) | O1-Pb2-O4 | 67.93(11) | ||||
O1-Pb2-O6 | 125.36(14) | O1-Pb2-N2 | 119.10(12) | ||||
O1-Pb2-N2 | 131.30(14) | O1-Pb2-N3 | 158.84(12) | ||||
O1-Pb2-N3 | 110.22(15) | O1-Pb2-N4 | 125.85(11) | ||||
O1-Pb2-N4 | 69.02(14) | O2-Pb2-O3 | 131.56(13) | ||||
O3-Pb2-O4 | 66.66(13) | Pb1-O1-Pb2 | 99.06(12) | ||||
O3-Pb2-O5 | 106.96(13) | Pb1-O1-Pb1i | 108.16(11) | ||||
O3-Pb2-O6 | 67.83(13) | O2-C11-C10 | 118.8(4) | ||||
O3-Pb2-N2 | 121.51(13) | O3-C31-O4 | 124.0(7) | ||||
O3-Pb2-N3 | 156.42(15) | O5-C36-O6 | 124.6(5) | ||||
O3-Pb2-N4 | 123.30(13) | Pb1-O2-Pb2 | 106.07(13) | ||||
O4-Pb2-O5 | 131.07(15) | Pb1 i-O4-Pb2 | 104.09(13) | ||||
O4-Pb2-O6 | 91.33(16) | ||||||
O4-Pb2-N2 | 68.81(14) | ||||||
O4-Pb2-N3 | 130.95(17) | ||||||
O4-Pb2-N4 | 77.90(16) | ||||||
O5-Pb2-O6 | 46.86(15) | ||||||
O5-Pb2-N2 | 76.77(16) | ||||||
O5-Pb2-N3 | 74.20(17) | ||||||
O5-Pb2-N4 | 129.58(15) | ||||||
O6-Pb2-N2 | 77.43(16) | ||||||
O6-Pb2-N3 | 120.39(17) | ||||||
O6-Pb2-N4 | 157.57(15) | ||||||
N2-Pb2-N3 | 81.96(16) | ||||||
N2-Pb2-N4 | 80.33(15) | ||||||
N3-Pb2-N4 | 58.44(17) | ||||||
Pb1-O1-Pb2 | 90.98(14) | ||||||
Pb1-O3-Pb2 | 99.01(13) | ||||||
Pb1-O3-Pb1i | 107.81(15) | ||||||
Pb1 i -O3-Pb2 | 108.59(13) | ||||||
Pb1 i -O3-C13 | 113.5(3) | ||||||
Pb1 i -O6-Pb2 | 105.74(17) | ||||||
O1-C1-O2 | 125.4(6) | ||||||
O5-C34-O6 | 124.8(7) |