From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
Halide | a |
| Δu TS / kcal mol-1 | σ |
|
---|---|---|---|---|---|
BrANb | 10 | 9.69 102 | 11.90 | 2.99 10-2 | 0.45 |
MBriB | 24 | 2.95 101 | 18.03 | 3.29 10-2 | 0.72 |
EtBriB | 11 | 1.70 102 | 11.57 | 6.94 10-2 | 0.51 |
MBrP | 3 | 5.39 103 | 9.00 | 4.61 10-2 | 0.19 |
ClPN | 26 | 6.11 | 21.98 | 5.30 10-2 | 0.68 |
PEBr | 1 | 3.00 105 | 8.71 | 6.67 10-2 | 6.65 10-2 |
ClAN | 11 | 5.01 101 | 13.97 | 4.84 10-2 | 0.46 |
AllBr | 1 | 8.00 105 | 9.84 | 9.18 10-2 | 5.88 10-2 |
BrPN | 1 | 2.11 106 | 6.71 | 3.44 10-2 | 7.26 10-2 |